Câu 3 : 

\(n_{HCl}=\dfrac{10\cdot21.9\%}{36.5}=0.06\left(mol\right)\)

\(AO+2HCl\rightarrow ACl_2+H_2O\)

\(0.03........0.06\)

\(M=\dfrac{2.4}{0.03}=80\left(\dfrac{g}{mol}\right)\)

\(\Rightarrow A=64\)

\(CuO\)

Câu 2 : 

$n_{CuO} = \dfrac{1,6}{80} = 0,02(mol)$
$n_{H_2SO_4} = \dfrac{100.20\%}{98} = \dfrac{10}{49}$

$CuO + H_2SO_4 \to CuSO_4 + H_2O$

$n_{CuO} < n_{H_2SO_4}$ nên $H_2SO_4 dư

Theo PTHH :
$n_{CuSO_4} = n_{H_2SO_4\ pư} = n_{CuO} = 0,02(mol)$
$m_{dd} = 1,6 + 100 = 101,6(gam)$

Vậy :

$C\%_{CuSO_4} = \dfrac{0,02.160}{101,6}.100\% = 3,15\%$

$C\%_{H_2SO_4\ dư} = \dfrac{100.20\% - 0,02.98}{101,6}.100\% = 17,6\%$

CÂU 2

m_H2SO4=100.20%=20(g)

n_H2SO4=20/98=0,2(mol)

n_CuO=1,6/80=0,02(mol)

PTHH : CuO+H₂SO₄-->CuSO₄+H₂O(1)

bài        0,02    0,2         0,02       0,02             (mol)

có:0,02/1<0,2/1---->CuO hết,H₂SO₄ dư

từ pt(1)-->n_CuSO4=0,02(mol)--->m_CuSO4=0,02.160=3,2(g)

khối lượng dd sau pư là:1,6+100-0,02.18=101,24(g)

-->C_%(CuSO4)=3,2/101,24.100%=3,16%

CÂU 3

m_HCl=10.21,9%=2,19(g)

-->n_HCl=2,19/36,5=0,06(mol)

gọi tên KL là M.M_M=M(g/mol)

PTHH: MO+2HCl-->MCl₂+H₂O(1)

          0,03     0,06                       (mol)

từ pt 1-->n_MO=0,03(mol)

--->M_MO=2,4/0,03=80(g/mol)

--->M=80-16=64(g/mol)

--->M là Cu

Ta có: \(n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)

a. PTHH: \(Mg+2HCl--->MgCl_2+H_2\)

Theo PT: \(n_{Mg}=n_{H_2}=0,2\left(mol\right)\)

=> \(m_{Mg}=0,2.24=4,8\left(g\right)\)

Theo PT: \(n_{HCl}=2.n_{Mg}=2.0,2=0,4\left(mol\right)\)

=> \(m_{HCl}=0,4.36.5=14,6\left(g\right)\)

=> \(C_{\%_{HCl}}=\dfrac{14,6}{200}.100\%=7,3\%\)

b. Ta có: \(m_{dd_{MgCl_2}}=4,8+200=204,8\left(g\right)\)

Theo PT: \(n_{MgCl_2}=n_{Mg}=0,2\left(mol\right)\)

=> \(m_{MgCl_2}=0,2.95=19\left(g\right)\)

=> \(C_{\%_{MgCl_2}}=\dfrac{19}{204,8}.100\%=9,28\%\)

Bài 1: 

PTHH: \(Mg+2HCl\rightarrow MgCl_2+H_2\uparrow\)

Ta có: \(n_{Mg}=\dfrac{4,8}{24}=0,2\left(mol\right)\)

\(\Rightarrow\left\{{}\begin{matrix}n_{HCl}=0,4\left(mol\right)\\n_{H_2}=0,2\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{ddHCl}=\dfrac{0,4\cdot36,5}{14,6\%}=100\left(g\right)\\V_{H_2}=0,2\cdot22,4=4,48\left(l\right)\end{matrix}\right.\)

Bài 2:

PTHH: \(2KOH+H_2SO_4\rightarrow K_2SO_4+2H_2O\)

Ta có: \(\left\{{}\begin{matrix}n_{KOH}=\dfrac{100\cdot11,2\%}{56}=0,2\left(mol\right)\\n_{H_2SO_4}=\dfrac{150\cdot9,8\%}{98}=0,15\left(mol\right)\end{matrix}\right.\)

Xét tỉ lệ: \(\dfrac{0,2}{2}< \dfrac{0,15}{1}\) \(\Rightarrow\) H₂SO₄ còn dư, KOH p/ứ hết

\(\Rightarrow\left\{{}\begin{matrix}n_{K_2SO_4}=0,1\left(mol\right)\\n_{H_2SO_4\left(dư\right)}=0,05\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{K_2SO_4}=0,1\cdot174=17,4\left(g\right)\\m_{H_2SO_4\left(dư\right)}=0,05\cdot98=4,9\left(g\right)\end{matrix}\right.\)

Mặt khác: \(m_{dd}=m_{ddKOH}+m_{ddH_2SO_4}=250\left(g\right)\)

\(\Rightarrow\left\{{}\begin{matrix}C\%_{K_2SO_4}=\dfrac{17,4}{250}\cdot100\%=6,96\%\\C\%_{H_2SO_4\left(dư\right)}=\dfrac{4,9}{250}\cdot100\%=1,96\%\end{matrix}\right.\)

Gọi \(\left\{{}\begin{matrix}n_{Al}=x\left(mol\right)\\n_{Fe}=y\left(mol\right)\end{matrix}\right.\)

\(n_{H_2}=\dfrac{4,48}{22,4}=0,2mol\)

\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)

\(Fe+2HCl\rightarrow FeCl_2+H_2\)

Theo pt: \(\Rightarrow\left\{{}\begin{matrix}3x+y=0,2\\27x+56y=5,5\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}x=\dfrac{19}{470}\\y=\dfrac{37}{470}\end{matrix}\right.\)

\(\%m_{Al}=\dfrac{\dfrac{19}{470}\cdot27}{5,5}\cdot100\%=19,84\%\)

\(\%m_{Fe}=100\%-19,84\%=80,16\%\)

Tính nồng độ phần trăm của dung dịch trong các trường hợp sau:

a) Cho 20 gam NaCl tan hoàn toàn trong 80 gam H2O?

-> mddNaCl= mNaCl+mH2O= 20+80=100(g)

=>C%ddNaCl= (mNaCl/mddNaCl).100%= (20/100).100= 20%

b) Cho 50 gam H2O vào 100 gam dung dịch HCl 10%?

mHCl= 10%.100= 10(g)

=> mddHCl(sau)= mddHCl(10%)+mH2O= 100+50=150(g)

=>C%ddHCl(sau)= (mHCl/mddHCl(sau)).100%= (10/150).100\(\approx6,667\%\)

c) Trộn 200 gam dung dịch HCl 20% với 100 gam dung dịch HCl 10%?

--

mHCl(tổng)= 200.20%+100.10%= 50(g)

mddHCl(tổng)=200+100=300(g)

=> C%ddHCl(tổng)= (mHCl(tổng)/ mddHCl(tổng)).100%= (50/300).100\(\approx16,667\%\)

d) Cho thêm 10 gam NaCl vào 90 gam dung dịch NaCl 30%?

---

mNaCl(trong dd 30%)= 30%.90=27(g)

=>mNaCl(tổng)= 10+27=37(g)

mddNaCl(tổng)=10+90=100(g)

=>C%ddNaCl(sau)= (mNaCl(tổng)/ mddNaCl(tổng)).100%= (37.100)/100= 37%

a) \(n_{Al}=\dfrac{8,64}{27}=0,32\left(mol\right)\)

\(n_{HCl}=\dfrac{365.10\%}{36,5}=1\left(mol\right)\)

PTHH: 2Al + 6HCl --> 2AlCl₃ + 3H₂

Xét tỉ lệ \(\dfrac{0,32}{2}< \dfrac{1}{6}\) => Al hết, HCl dư

PTHH: 2Al + 6HCl --> 2AlCl₃ + 3H₂

         0,32-->0,96---->0,32--->0,48

=> \(V_{H_2}=0,48.22,4=10,752\left(l\right)\)

b) Trong Y chứa AlCl₃ và HCl dư

\(m_{AlCl_3}=0,32.133,5=42,72\left(g\right)\)

c) m_{dd sau pư} = 8,64 + 365 - 0,48.2 = 372,68 (g)

 \(\left\{{}\begin{matrix}C\%\left(AlCl_3\right)=\dfrac{42,72}{372,68}.100\%=11,463\%\\C\%\left(HCldư\right)=\dfrac{\left(1-0,96\right).36,5}{372,68}.100\%=0,392\%\end{matrix}\right.\)

a) \(n_{FeCl_3}=\dfrac{16,25}{162,5}=0,1\left(mol\right)\)

PTHH: Fe₂O₃ + 6HCl --> 2FeCl₃ + 3H₂O

            0,05<----0,3<-----0,1

=> \(m_{Fe_2O_3}=0,05.160=8\left(g\right)\)

b) 

\(m_{HCl\left(bd\right)}=91,25.16\%=14,6\left(g\right)\)

m_{dd sau pư} = 8 + 91,25 = 99,25 (g)

\(\left\{{}\begin{matrix}C\%\left(FeCl_3\right)=\dfrac{16,25}{99,25}.100\%=16,373\%\\C\%\left(HCldư\right)=\dfrac{14,6-0,3.36,5}{99,25}.100\%=3,678\%\end{matrix}\right.\)

\(a,n_{H_2}=\dfrac{2,576}{22,4}=0,115\left(mol\right)\\ Đặt:n_{Mg}=a\left(mol\right);n_{Al}=b\left(mol\right)\left(a,b>0\right)\\ Mg+2HCl\rightarrow MgCl_2+H_2\\ 2Al+6HCl\rightarrow2AlCl_3+3H_2\\ \Rightarrow\left\{{}\begin{matrix}95a+133,5b=10,475\\a+1,5b=0,115\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,04\\b=0,05\end{matrix}\right.\\ \%m_{Mg}=\dfrac{0,04.24}{0,04.24+0,05.27}.100\approx41,558\%\Rightarrow\%m_{Al}\approx58,442\%\\ b,n_{HCl}=2.n_{H_2}=2.0,115=0,23\left(mol\right)\\ \Rightarrow x=C\%_{ddHCl}=\dfrac{0,23.36,5}{100}.100=8,395\%\)

Đáp án C

Bảo toàn nguyên tố Hidro và Clo: n_Cl^– = n_HCl = 2n_H2 = 1 mol.

⇒ m_{muối khan} = m_{kim loại} + m_Cl^– = 20 + 1 × 35,5 = 55,5(g)